GHS_USA_EN_AF---M035_-----_3

RENNER ITALIA S.P.A. AF---M035/----- - ELECTROSTATIC ADDITIVE Revision nr.3 Dated 3/27/2025 Printed on 12/17/2025 Page n. 1 / 13 Replaced revision:2 (Dated 3/27/2025) EN EPY 11.7.1 - SDS 1004.14 Safety Data Sheet According to U.S.A. Federal Hazcom 2012 1. Identification 1.1. Product identifier Code: AF---M035/----- Product name ELECTROSTATIC ADDITIVE 1.2. Relevant identified uses of the substance or mixture and uses advised against Intended use ELECTROSTATIC ADDITIVE Identified Uses Industrial Professional Consumer Additives for PU systems for industrial and professional uses - Uses Advised Against All uses not mentioned among recommended uses. 1.3. Details of the supplier of the safety data sheet Name RENNER ITALIA S.P.A. Full address Via Ronchi Inferiore, 34 District and Country 40061 Minerbio (BO) Italia Tel. +39 051-6618211 Fax +39 051-6606312 e-mail address of the competent person responsible for the Safety Data Sheet [email protected] 1.4. Emergency telephone number For urgent inquiries refer to For 24/7 multilingual advice for a spill, leak, fire, exposure, or accident call CHEMTREC and provide Chemtrec Customer Number CCN1016294 Region: USA, Canada (United States, English only) Phone Number +1 703-741-5970 Region: Central America Phone Number + 52 55 8526 4930 Region: South America Phone Number +55 11 4349 1359 2. Hazards identification 2.1. Classification of the substance or mixture The product is classified as hazardous pursuant to the provisions set forth in OSHA Hazard Communication Standard (HCS) (29 CFR 1910.1200). The product thus requires a safety datasheet. Any additional information concerning the risks for health and/or the environment are given in sections 11 and 12 of this sheet. Classification and Hazard Statement Flammable liquid, category 3 Flammable liquid and vapour. Acute toxicity, category 4 Harmful if swallowed. Acute toxicity, category 4 Harmful in contact with skin. Skin corrosion, category 1 Causes severe skin burns and eye damage. Serious eye damage, category 1 Causes serious eye damage. Specific target organ toxicity - single exposure, category 3 May cause respiratory irritation. Specific target organ toxicity - single exposure, category 3 May cause drowsiness or dizziness.RENNER ITALIA S.P.A. AF---M035/----- - ELECTROSTATIC ADDITIVE Revision nr.3 Dated 3/27/2025 Printed on 12/17/2025 Page n. 2 / 13 Replaced revision:2 (Dated 3/27/2025) EN EPY 11.7.1 - SDS 1004.14 2. Hazards identification ... / >> Hazard pictograms: Signal words: Danger Hazard statements: H226 Flammable liquid and vapour. H302+H312 Harmful if swallowed or in contact with skin. H314 Causes severe skin burns and eye damage. H335 May cause respiratory irritation. H336 May cause drowsiness or dizziness. Precautionary statements: Prevention: P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P260 Do not breathe dust / fume / gas / mist / vapours / spray. P242 Use only non-sparking tools. P280 Wear protective gloves/ protective clothing / eye protection / face protection. P270 Do not eat, drink or smoke when using this product. P271 Use only outdoors or in a well-ventilated area. P264 Wash hands thoroughly after handling. P240 Ground / bond container and receiving equipment. P243 Take precautionary measures against static discharge. P241 Use explosion-proof [electrical / ventilating / lighting] equipment. Response: P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P301+P330+P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water / shower. P310 Immediately call a POISON CENTER / doctor. P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. P330 Rinse mouth. P302+P352 IF ON SKIN: Wash with plenty of water. P362+P364 Take off contaminated clothing and wash it before reuse. P370+P378 In case of fire: use carbon dioxide, foam, powder and water spray to extinguish. P301+P312 IF SWALLOWED: Call a POISON CENTER / doctor if you feel unwell. P363 Wash contaminated clothing before reuse. Storage: P403+P235 Store in a well-ventilated place. Keep cool. P403+P233 Store in a well-ventilated place. Keep container tightly closed. P405 Store locked up. Disposal: P501 Dispose of contents / container in accordance with regulation in force. 2.2. Other hazards Environmental classification as for Reg. (EC) 1272/2008 (CLP): The product is classified as hazardous for environment pursuant to the provisions set forth in EC Regulation 1272/2008 (CLP). Classification and Hazard Statement Hazardous to the aquatic environment, acute toxicity, category 1 Very toxic to aquatic life. Hazardous to the aquatic environment, chronic toxicity, category 1 Very toxic to aquatic life with long lasting effects. Hazard pictograms: Signal words: Warning Hazard statements:RENNER ITALIA S.P.A. AF---M035/----- - ELECTROSTATIC ADDITIVE Revision nr.3 Dated 3/27/2025 Printed on 12/17/2025 Page n. 3 / 13 Replaced revision:2 (Dated 3/27/2025) EN EPY 11.7.1 - SDS 1004.14 2. Hazards identification ... / >> H400 Very toxic to aquatic life. H410 Very toxic to aquatic life with long lasting effects. Precautionary statements: Prevention: P273 Avoid release to the environment. Response: P391 Collect spillage. Storage: -- Disposal: P501 Dispose of contents / container in accordance with regulation in force. Information not available 3. Composition/information on ingredients 3.2. Mixtures Contains: Identification x = Conc. % Classification: N-BUTYL ACETATE INDEX 607-025-00-1 45 ≤ x < 50 Flammable liquid, category 3 H226, Specific target organ toxicity - single exposure, category 3 H336 EC 204-658-1 CAS 123-86-4 REACH Reg. 01-2119485493-29 Quaternary ammonium compounds, C12-14-alkylethyldimethyl, Et sulfates 25 ≤ x < 26.4 Acute toxicity, category 3 H311, Acute toxicity, category 4 H302, Skin corrosion, category 1C H314, Serious eye damage, category 1 H318, Hazardous to the aquatic environment, acute toxicity, category 1 H400 M=1, Hazardous to the aquatic environment, chronic toxicity, category 1 H410 M=1 EC 939-607-9 CAS 1474044-65-9 REACH Reg. 01-2119977130-42-XXXX ISO-BUTANOL INDEX 603-108-00-1 25 ≤ x < 30 Flammable liquid, category 3 H226, Serious eye damage, category 1 H318, Skin irritation, category 2 H315, Specific target organ toxicity - single exposure, category 3 H335, Specific target organ toxicity - single exposure, category 3 H336 EC 201-148-0 CAS 78-83-1 REACH Reg. 01-2119484609-23-xxxx * There is a batch to batch variation. The full wording of hazard (H) phrases is given in section 16 of the sheet. 4. First-aid measures 4.1. Description of first aid measures In case of doubt or in the presence of symptoms contact a doctor and show him this document. In case of more severe symptoms, ask for immediate medical aid. EYES: Remove, if present, contact lenses if the situation allows you to do so easily. Wash immediately with plenty of water for at least 15 minutes, opening the eyelids fully. Get medical advice/attention. SKIN: Take off immediately all contaminated clothing. Wash immediately and thoroughly with running water (and soap if possible). Get medical advice/attention. Avoid further contact with contaminated clothing. INGESTION: Do not induce vomiting unless explicitly authorised by a doctor. Rinse your mouth with running water. Do not give anything by mouth to an unconscious person. Get medical advice/attention. INHALATION: Remove victim to fresh air, away from the accident scene. In the event of respiratory symptoms (coughing, wheezing, breathing difficulty, asthma) keep the victim in a comfortable position for breathing. If necessary administer oxygen. If the subject stops breathing, administer artificial respiration. Get medical advice/attention. Rescuer protection It is good practice for rescuers lending support to a person who has been exposed to a chemical substance or to a mixture to wear personal protective equipment. The nature of such protection depends on the hazard level of the substance or mixture, on the type of exposure andRENNER ITALIA S.P.A. AF---M035/----- - ELECTROSTATIC ADDITIVE Revision nr.3 Dated 3/27/2025 Printed on 12/17/2025 Page n. 4 / 13 Replaced revision:2 (Dated 3/27/2025) EN EPY 11.7.1 - SDS 1004.14 4. First-aid measures ... / >> on the extent of the contamination. In the absence of other more specific indications, use of disposable gloves in the event of possible contact with body fluids is recommended. For the type of PPE suitable for the characteristics of the substance or mixture, see section 8. 4.2. Most important symptoms and effects, both acute and delayed Specific information on symptoms and effects caused by the product are unknown. DELAYED EFFECTS: Based on the information currently available, there are no known cases of delayed effects following exposure to this product. 4.3. Indication of any immediate medical attention and special treatment needed If symptoms occur, whether acute or delayed, consult a doctor. Means to have available in the workplace for specific and immediate treatment Running water for skin and eye wash. 5. Fire-fighting measures 5.1. Extinguishing media SUITABLE EXTINGUISHING EQUIPMENT Extinguishing substances are: carbon dioxide, foam, chemical powder. For product loss or leakage that has not caught fire, water spray can be used to disperse flammable vapours and protect those trying to stem the leak. UNSUITABLE EXTINGUISHING EQUIPMENT Do not use jets of water. Water is not effective for putting out fires but can be used to cool containers exposed to flames to prevent explosions. 5.2. Special hazards arising from the substance or mixture HAZARDS CAUSED BY EXPOSURE IN THE EVENT OF FIRE Excess pressure may form in containers exposed to fire at a risk of explosion. Do not breathe combustion products. 5.3. Advice for firefighters GENERAL INFORMATION Use jets of water to cool the containers to prevent product decomposition and the development of substances potentially hazardous for health. Always wear full fire prevention gear. Collect extinguishing water to prevent it from draining into the sewer system. Dispose of contaminated water used for extinction and the remains of the fire according to applicable regulations. SPECIAL PROTECTIVE EQUIPMENT FOR FIRE-FIGHTERS Normal fire fighting clothing i.e. fire kit (BS EN 469), gloves (BS EN 659) and boots (HO specification A29 and A30) in combination with self-contained open circuit positive pressure compressed air breathing apparatus (BS EN 137). 6. Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Block the leakage if there is no hazard. Wear suitable protective equipment (including personal protective equipment referred to under Section 8 of the safety data sheet) to prevent any contamination of skin, eyes and personal clothing. These indications apply for both processing staff and those involved in emergency procedures. 6.2. Environmental precautions The product must not penetrate into the sewer system or come into contact with surface water or ground water. 6.3. Methods and material for containment and cleaning up Collect the leaked product into a suitable container. Evaluate the compatibility of the container to be used, by checking section 10. Absorb the remainder with inert absorbent material. Make sure the leakage site is well aired. Contaminated material should be disposed of in compliance with the provisions set forth in point 13. 6.4. Reference to other sections Any information on personal protection and disposal is given in sections 8 and 13.RENNER ITALIA S.P.A. AF---M035/----- - ELECTROSTATIC ADDITIVE Revision nr.3 Dated 3/27/2025 Printed on 12/17/2025 Page n. 5 / 13 Replaced revision:2 (Dated 3/27/2025) EN EPY 11.7.1 - SDS 1004.14 7. Handling and storage 7.1. Precautions for safe handling Keep away from heat, sparks and naked flames; do not smoke or use matches or lighters. Without adequate ventilation, vapours may accumulate at ground level and, if ignited, catch fire even at a distance, with the danger of backfire. Avoid bunching of electrostatic charges. Do not eat, drink or smoke during use. Remove any contaminated clothes and personal protective equipment before entering places in which people eat. Avoid leakage of the product into the environment. 7.2. Conditions for safe storage, including any incompatibilities Store only in the original container. Store in a cool and well ventilated place, keep far away from sources of heat, naked flames and sparks and other sources of ignition. Keep containers away from any incompatible materials, see section 10 for details. 7.3. Specific end use(s) Information not available 8. Exposure controls/personal protection 8.1. Control parameters Regulatory references: USA NIOSH-REL NIOSH publication No. 2005-149, 3th printing, 2007. USA OSHA-PEL Occupational Exposure Limits - Limits for Air Contaminants TABLE Z-1-1910.1000. USA CAL/OSHA-PEL California Division of Occupational Safety and Health (Cal-OSHA) Permissible Exposure Limits (PELs). EU OEL EU Directive (EU) 2022/431; Directive (EU) 2019/1831; Directive (EU) 2019/130; Directive (EU) 2019/983; Directive (EU) 2017/2398; Directive (EU) 2017/164; Directive 2009/161/EU; Directive 2006/15/EC; Directive 2004/37/EC; Directive 2000/39/EC; Directive 98/24/EC; Directive 91/322/EEC. TLV-ACGIH ACGIH 2025 ISO-BUTANOL Threshold Limit Value Type Country TWA/8h STEL/15min Remarks / Observations mg/m3 ppm mg/m3 ppm TLV-ACGIH - 152 50 OSHA USA 300 100 CAL/OSHA USA 150 50 NIOSH USA 150 50 N-BUTYL ACETATE Threshold Limit Value Type Country TWA/8h STEL/15min Remarks / Observations mg/m3 ppm mg/m3 ppm OEL EU 241 50 723 150 TLV-ACGIH - 50 150 OSHA USA 710 150 CAL/OSHA USA 710 150 950 200 NIOSH USA 710 150 950 200 Legend: (C) = CEILING ; INHAL = Inhalable Fraction ; RESP = Respirable Fraction ; THORA = Thoracic Fraction. 8.2. Exposure controls Take the normal precautions for handling chemicals and apply an adequate standard of workplace hygiene. Users must assess the risks in their workplace and adopt: - Primary collective protective measures such as adequate natural ventilation and local extraction - Personal protective equipment to manage the combination of residual risks Personal protective equipment varies according to the possible exposure and hazardousness of the working conditions, so the final choice depends on the risk assessment. HAND PROTECTIONRENNER ITALIA S.P.A. AF---M035/----- - ELECTROSTATIC ADDITIVE Revision nr.3 Dated 3/27/2025 Printed on 12/17/2025 Page n. 6 / 13 Replaced revision:2 (Dated 3/27/2025) EN EPY 11.7.1 - SDS 1004.14 8. Exposure controls/personal protection ... / >> Use category III chemical resistant gloves according to the EN 374 standard Brief contact (splash protection) – non-exhaustive list Suitable material: NITRILE RUBBER (NBR) Glove thickness: greater than 0.4 mm Breakthrough time: from 30 to 60 minutes Breakthrough index: at least 2 The gloves must be replaced if there are signs of deterioration. In any case, users must assess the risks to determine the most suitable type of glove for the conditions of use SKIN PROTECTION Wear antistatic work clothes and safety footwear that complies with EN ISO 20344. EYE PROTECTION Wear safety mask glasses (UNI EN ISO 16321-1). RESPIRATORY PROTECTION Use a mask with EN140 and/or EN136 approval, with a type A filter (for organic vapours with boiling points > 65°C; EN 14387) of a class (1, 2, 3) to be chosen according to the risk assessment in the workplace. ENVIRONMENTAL EXPOSURE CONTROLS The emissions generated by manufacturing processes, including those generated by ventilation equipment, should be checked to ensure compliance with environmental standards. 9. Physical and chemical properties 9.1. Information on basic physical and chemical properties Properties Value Information Appearance liquid Colour colourless Odour pungent Odour threshold not available pH not available Melting point / freezing point not available Initial boiling point > 65 °C (149 °F) Boiling range not available Flash point 27 °C (80,6 °F) Evaporation rate not available Flammability flammable liquid Lower explosive limit not available Upper explosive limit not available Vapour pressure not available Vapour density not available Relative density 0.903 Solubility soluble in water Partition coefficient: n-octanol/water not available Auto-ignition temperature not available Decomposition temperature not available Viscosity not available Explosive properties not applicable Oxidising properties not applicable 9.2. Other information Total solids (250°C / 482°F) 25,00 % VOC : 75,00 % - 677,00 g/litre 10. Stability and reactivity 10.1. Reactivity There are no particular risks of reaction with other substances in normal conditions of use. N-BUTYL ACETATERENNER ITALIA S.P.A. AF---M035/----- - ELECTROSTATIC ADDITIVE Revision nr.3 Dated 3/27/2025 Printed on 12/17/2025 Page n. 7 / 13 Replaced revision:2 (Dated 3/27/2025) EN EPY 11.7.1 - SDS 1004.14 10. Stability and reactivity ... / >> Decomposes on contact with: water. 10.2. Chemical stability The product is stable in normal conditions of use and storage. 10.3. Possibility of hazardous reactions The vapours may also form explosive mixtures with the air. N-BUTYL ACETATE Risk of explosion on contact with: strong oxidising agents.May react dangerously with: alkaline hydroxides,potassium tert-butoxide.Forms explosive mixtures with: air. 10.4. Conditions to avoid Avoid overheating. Avoid bunching of electrostatic charges. Avoid all sources of ignition. N-BUTYL ACETATE Avoid exposure to: moisture,sources of heat,naked flames. 10.5. Incompatible materials N-BUTYL ACETATE Incompatible with: water,nitrates,strong oxidants,acids,alkalis,zinc. 10.6. Hazardous decomposition products In the event of thermal decomposition or fire, gases and vapours that are potentially dangerous to health may be released. 11. Toxicological information In the absence of experimental data for the product itself, health hazards are evaluated according to the properties of the substances it contains, using the criteria specified in the applicable regulation for classification. It is therefore necessary to take into account the concentration of the individual hazardous substances indicated in section 3, to evaluate the toxicological effects of exposure to the product. 11.1. Information on toxicological effects Metabolism, toxicokinetics, mechanism of action and other information Information not available Information on likely routes of exposure Information not available Delayed and immediate effects as well as chronic effects from short and long-term exposure Information not available Interactive effects Information not available ACUTE TOXICITY ISO-BUTANOL LD50 (Oral): > 2830 mg/kg LD50 (Dermal): 2460 mg/kg LC50 (Inhalation vapours): 24.6 mg/l/4h N-BUTYL ACETATE LD50 (Oral): 10736 mg/kg ratto LD50 (Dermal): > 14112 mg/kg LC50 (Inhalation vapours): > 0.74 mg/l/4h Quaternary ammonium compounds, C12-14-alkylethyldimethyl, Et sulfates LD50 (Oral): 570 mg/kg LD50 (Dermal): 528 mg/kg SKIN CORROSION / IRRITATIONRENNER ITALIA S.P.A. AF---M035/----- - ELECTROSTATIC ADDITIVE Revision nr.3 Dated 3/27/2025 Printed on 12/17/2025 Page n. 8 / 13 Replaced revision:2 (Dated 3/27/2025) EN EPY 11.7.1 - SDS 1004.14 11. Toxicological information ... / >> Corrosive for the skin SERIOUS EYE DAMAGE / IRRITATION Causes serious eye damage RESPIRATORY OR SKIN SENSITISATION Does not meet the classification criteria for this hazard class GERM CELL MUTAGENICITY Does not meet the classification criteria for this hazard class CARCINOGENICITY Does not meet the classification criteria for this hazard class REPRODUCTIVE TOXICITY Does not meet the classification criteria for this hazard class STOT - SINGLE EXPOSURE May cause respiratory irritation May cause drowsiness or dizziness STOT - REPEATED EXPOSURE Does not meet the classification criteria for this hazard class ASPIRATION HAZARD Does not meet the classification criteria for this hazard class 12. Ecological information This product is dangerous for the environment and highly toxic for aquatic organisms. In the long term, it has negative effects on the aquatic environment. 12.1. Toxicity ISO-BUTANOL LC50 - for Fish 1430 mg/l/96h Pimephales promelas - Fish EC50 - for Crustacea 1100 mg/l/48h Daphnia magna EC50 - for Algae / Aquatic Plants 1799 mg/l/72h Presudokirchneriella subcapitata Chronic NOEC for Crustacea 20 mg/l Daphnia magna N-BUTYL ACETATE LC50 - for Fish 18 mg/l/96h Pimephales promelas EC50 - for Crustacea 44 mg/l/48h Daphnia magna EC50 - for Algae / Aquatic Plants 674.7 mg/l/72h Desmodesmus subcapitata Chronic NOEC for Crustacea 23 mg/l 21 d Chronic NOEC for Algae / Aquatic Plants 196 mg/l/72h Scenedesmus subspicatusRENNER ITALIA S.P.A. AF---M035/----- - ELECTROSTATIC ADDITIVE Revision nr.3 Dated 3/27/2025 Printed on 12/17/2025 Page n. 9 / 13 Replaced revision:2 (Dated 3/27/2025) EN EPY 11.7.1 - SDS 1004.14 12. Ecological information ... / >> Quaternary ammonium compounds, C12-14-alkylethyldimethyl, Et sulfates LC50 - for Fish 13.8 mg/l/96h EC50 - for Crustacea 0.036 mg/l/48h EC50 - for Algae / Aquatic Plants 0.14 mg/l/72h LC10 for Fish 0.032 mg/l/96h EC10 for Algae / Aquatic Plants 0.001 mg/l/72h 12.2. Persistence and degradability ISO-BUTANOL Solubility in water 1000 - 10000 mg/l Rapidly degradable N-BUTYL ACETATE Solubility in water 1000 - 10000 mg/l Rapidly degradable Quaternary ammonium compounds, C12-14-alkylethyldimethyl, Et sulfates Solubility in water 1100 mg/l Inherently degradable 12.3. Bioaccumulative potential ISO-BUTANOL Partition coefficient: n-octanol/water 1 N-BUTYL ACETATE Partition coefficient: n-octanol/water 2.3 BCF 15.3 12.4. Mobility in soil ISO-BUTANOL Partition coefficient: soil/water 0.31 N-BUTYL ACETATE Partition coefficient: soil/water < 3 12.5. Results of PBT and vPvB assessment On the basis of available data, the product does not contain any PBT or vPvB in percentage ≥ than 0,1%. 12.6. Other adverse effects Information not available 13. Disposal considerations 13.1. Waste treatment methods For disposal or recovery in EU countries , use the relevant waste code (EWC code) identified in the European Waste Catalogue. The producer of the waste must assign the EWC code according to the sector and type of process. Disposal must be carried out by an authorised waste management company.RENNER ITALIA S.P.A. AF---M035/----- - ELECTROSTATIC ADDITIVE Revision nr.3 Dated 3/27/2025 Printed on 12/17/2025 Page n. 10 / 13 Replaced revision:2 (Dated 3/27/2025) EN EPY 11.7.1 - SDS 1004.14 After the producer of the waste has assigned the EWC code, the contaminated packaging must be sent for recovery or disposal in compliance with the European waste management regulations. Disposal must be carried out by an authorised waste management company. Disposal or Recovery Outside the EU Disposal or recovery in non-EU countries must comply with applicable national or local regulations. The following are to be considered special waste for disposal: products used in accordance with their intended use, unused products, and products that are deteriorated and/or degraded. Waste characterization is the responsibility of the waste producer and must comply with applicable national or local regulations. Disposal or Recovery of Contaminated Packaging Outside the EU For the disposal or recovery of contaminated packaging in non-EU countries, applicable national or local regulations must be observed. Uncleaned empty packaging is to be considered special waste. Waste transportation may be subject to regulations on transportation of hazardous goods. Do not discharge, either directly or indirectly, into water bodies, groundwater, soil or public treatment plants. 14. Transport information 14.1. UN number ADR / RID, IMDG, IATA: UN 3470 14.2. UN proper shipping name ADR / RID: PAINT RELATED MATERIAL IMDG: PAINT RELATED MATERIAL IATA: PAINT RELATED MATERIAL 14.3. Transport hazard class(es) ADR / RID: Class: 8 Label: 8 (3) IMDG: Class: 8 Label: 8 (3) IATA: Class: 8 Label: 8 (3) 14.4. Packing group ADR / RID, IMDG, IATA: II 14.5. Environmental hazards ADR / RID: NO IMDG: not marine pollutant IATA: NO 14.6. Special precautions for user ADR / RID: HIN - Kemler: 83 Limited Quantities: 1 L Tunnel restriction code: (D/E) Special provision: 163, 367 IMDG: EMS: F-E, S-C Limited Quantities: 1 L IATA: Cargo: Maximum quantity: 30 L Packaging instructions: 855 Passengers: Maximum quantity: 1 L Packaging instructions: 851 Special provision: A72, A192 14.7. Transport in bulk according to Annex II of Marpol and the IBC Code Information not relevant